What does entropy measure in a thermodynamic system?

Study for the Massachusetts 3rd Class Engineer Exam. Access flashcards and multiple choice questions with hints and explanations. Prepare for success on your exam!

Entropy is a fundamental concept in thermodynamics and is particularly associated with the second law of thermodynamics. It quantifies the degree of disorder or randomness in a system. More specifically, entropy measures the amount of energy in a system that is not available to do work. As a system becomes more disordered, its entropy increases, indicating that less energy is available for performing useful tasks.

When a system undergoes a spontaneous process, the total entropy of the system and its surroundings tends to increase, which means that energy is dispersed and becomes unavailable for work. This aligns with the idea that as processes occur naturally, they tend to increase the disorder of the system.

In contrast, the first choice refers to total energy available for work, which is not what entropy measures; instead, it focuses on the ideal energy available rather than the disordered energy. The third option, relating to the overall energy gained by a system, does not directly address the concept of energy distribution and availability as entropy does. Lastly, measuring the pressure of a system at equilibrium pertains to state variables in thermodynamics but does not relate to the concept of entropy and disorder within the system.

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